Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry.
نویسندگان
چکیده
A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 131 38 شماره
صفحات -
تاریخ انتشار 2009